Pine Tar
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Pine tar is a form of
wood tar Tar is a dark brown or black viscous liquid of hydrocarbons and free carbon, obtained from a wide variety of organic materials through destructive distillation. Tar can be produced from coal, wood, petroleum, or peat. "a dark brown or black bi ...
produced by the high temperature
carbonization Carbonization is the conversion of organic matters like plants and dead animal remains into carbon through destructive distillation. Complexity in carbonization Carbonization is a pyrolytic reaction, therefore, is considered a complex process ...
of
pine A pine is any conifer tree or shrub in the genus ''Pinus'' () of the family Pinaceae. ''Pinus'' is the sole genus in the subfamily Pinoideae. The World Flora Online created by the Royal Botanic Gardens, Kew and Missouri Botanical Garden accep ...
wood in
anoxic The term anoxia means a total depletion in the level of oxygen, an extreme form of hypoxia or "low oxygen". The terms anoxia and hypoxia are used in various contexts: * Anoxic waters, sea water, fresh water or groundwater that are depleted of diss ...
conditions (dry distillation or
destructive distillation Destruction may refer to: Concepts * Destruktion, a term from the philosophy of Martin Heidegger * Destructive narcissism, a pathological form of narcissism * Self-destructive behaviour, a widely used phrase that ''conceptualises'' certain kind ...
). The wood is rapidly decomposed by applying heat and pressure in a closed container; the primary resulting products are
charcoal Charcoal is a lightweight black carbon residue produced by strongly heating wood (or other animal and plant materials) in minimal oxygen to remove all water and volatile constituents. In the traditional version of this pyrolysis process, cal ...
and pine
tar Tar is a dark brown or black viscous liquid of hydrocarbons and free carbon, obtained from a wide variety of organic materials through destructive distillation. Tar can be produced from coal, wood, petroleum, or peat. "a dark brown or black bit ...
. Pine tar consists primarily of
aromatic hydrocarbons Aromatic compounds, also known as "mono- and polycyclic aromatic hydrocarbons", are organic compounds containing one or more aromatic rings. The parent member of aromatic compounds is benzene. The word "aromatic" originates from the past groupin ...
, tar acids, and tar bases. Components of tar vary according to the
pyrolytic The pyrolysis (or devolatilization) process is the thermal decomposition of materials at elevated temperatures, often in an inert atmosphere. It involves a change of chemical composition. The word is coined from the Greek-derived elements ''pyr ...
process (e.g. method, duration, temperature) and origin of the wood (e.g. age of pine trees, type of soil, and moisture conditions during tree growth). The choice of wood, design of
kiln A kiln is a thermally insulated chamber, a type of oven, that produces temperatures sufficient to complete some process, such as hardening, drying, or chemical changes. Kilns have been used for millennia to turn objects made from clay int ...
, burning, and collection of the tar can vary. Only pine stumps and roots are used in the traditional production of pine tar. Pine tar has a long history as a wood preservative, as a wood sealant for maritime use, in roofing construction and maintenance, in
soap Soap is a salt of a fatty acid used in a variety of cleansing and lubricating products. In a domestic setting, soaps are surfactants usually used for washing, bathing, and other types of housekeeping. In industrial settings, soaps are use ...
s, and in the treatment of
carbuncle A carbuncle is a cluster of boils caused by bacterial infection, most commonly with ''Staphylococcus aureus'' or ''Streptococcus pyogenes''. The presence of a carbuncle is a sign that the immune system is active and fighting the infection. The ...
s and
skin diseases A skin condition, also known as cutaneous condition, is any medical condition that affects the integumentary system—the organ system that encloses the body and includes skin, nails, and related muscle and glands. The major function of thi ...
, such as
psoriasis Psoriasis is a long-lasting, noncontagious autoimmune disease characterized by raised areas of abnormal skin. These areas are red, pink, or purple, dry, itchy, and scaly. Psoriasis varies in severity from small, localized patches to complete ...
,
eczema Dermatitis is inflammation of the skin, typically characterized by itchiness, redness and a rash. In cases of short duration, there may be small blisters, while in long-term cases the skin may become thickened. The area of skin involved can ...
, and
rosacea Rosacea is a long-term skin condition that typically affects the face. It results in redness, pimples, swelling, and small and superficial dilated blood vessels. Often, the nose, cheeks, forehead, and chin are most involved. A red, enlarg ...
. It is used in
baseball Baseball is a bat-and-ball sport played between two teams of nine players each, taking turns batting and fielding. The game occurs over the course of several plays, with each play generally beginning when a player on the fielding tea ...
to enhance the grip of a hitter's bat; it is also sometimes used by
pitcher In baseball, the pitcher is the player who throws ("pitches") the baseball from the pitcher's mound toward the catcher to begin each play, with the goal of retiring a batter, who attempts to either make contact with the pitched ball or draw ...
s to improve their grip on the ball, in violation of the rules.


History

Pine tar has long been used in Scandinavian nations as a preservative for wood which may be exposed to harsh conditions, including outdoor furniture and ship decking and rigging. The high-grade pine tar used in this application is often called Stockholm Tar since, for many years, a single company held a
royal monopoly A legal monopoly, statutory monopoly, or ''de jure'' monopoly is a monopoly that is protected by law from competition. A statutory monopoly may take the form of a government monopoly where the state owns the particular means of production or govern ...
on its export out of
Stockholm, Sweden Stockholm () is the capital and largest city of Sweden as well as the largest urban area in Scandinavia. Approximately 980,000 people live in the municipality, with 1.6 million in the urban area, and 2.4 million in the metropoli ...
. It is also known as "
Archangel Archangels () are the second lowest rank of angel in the hierarchy of angels. The word ''archangel'' itself is usually associated with the Abrahamic religions, but beings that are very similar to archangels are found in a number of other relig ...
Tar". Tar and pitch for maritime use was in such demand that it became an important export for the American colonies, which had extensive pine forests. North Carolinians became known as "
Tar Heel Tar Heel is a nickname applied to the U.S. state of North Carolina. It is also the nickname of the University of North Carolina athletic teams, students, alumni, and fans. The origins of the Tar Heel nickname trace back to North Carolina's promi ...
s."


Use

Pine tar was used as a preservative on the bottoms of traditional Nordic-style skis until modern synthetic materials replaced wood in their construction. It also helped waxes adhere, which aided such skis’ grip and glide. Pine tar is widely used as a
veterinary Veterinary medicine is the branch of medicine that deals with the prevention, management, diagnosis, and treatment of disease, disorder, and injury in animals. Along with this, it deals with animal rearing, husbandry, breeding, research on nutri ...
care product, particularly as an
antiseptic An antiseptic (from Greek ἀντί ''anti'', "against" and σηπτικός ''sēptikos'', "putrefactive") is an antimicrobial substance or compound that is applied to living tissue/skin to reduce the possibility of infection, sepsis, or putre ...
and
hoof The hoof (plural: hooves) is the tip of a toe of an ungulate mammal, which is covered and strengthened with a thick and horny keratin covering. Artiodactyls are even-toed ungulates, species whose feet have an even number of digits, yet the rum ...
care treatment for horses and cattle. It also has been used when chickens start pecking the low hen. Applying a smear of pine tar on the hens' wound acts as a natural germicidal/antibacterial agent that discourages continued attacks on the affected hen due to its foreign texture. Pine tar is used as a softening solvent in the rubber industry, for treating and fabricating construction materials, and in special paints.


As a wood preservative

Pine tar is combined with gum
turpentine Turpentine (which is also called spirit of turpentine, oil of turpentine, terebenthene, terebinthine and (colloquially) turps) is a fluid obtained by the distillation of resin harvested from living trees, mainly pines. Mainly used as a special ...
and boiled
linseed oil Linseed oil, also known as flaxseed oil or flax oil (in its edible form), is a colourless to yellowish oil obtained from the dried, ripened seeds of the flax plant (''Linum usitatissimum''). The oil is obtained by pressing, sometimes followed by ...
to create a wood preservative. First, a thin coat is applied using a mixture with a greater proportion of turpentine. This allows it to permeate deeper into the
oakum Oakum is a preparation of tarred fibre used to seal gaps. Its main traditional applications were in shipbuilding, for caulking or packing the joints of timbers in wooden vessels and the deck planking of iron and steel ships; in plumbing, for s ...
and fibre of the wood and lets the tar seep into any pinholes and larger gaps that might be in the planks. The tar weeps out to the exterior and indicates where the boat needs the most attention. This is followed with a thicker standard mix. Such treatments, while effective, must be continually reapplied.


Weatherproofing rope

Traditionally, hemp and other natural fibers were the norm for rope production. Such rope would quickly rot when exposed to rain, and was typically tarred to preserve it. The tar would stain the hands of ship's crews, and British Navy seamen became known as "tars."


Baseball

Pine tar is applied to the handles of
baseball bats A baseball bat is a smooth wooden or metal club used in the sport of baseball to hit the ball after it is thrown by the pitcher. By regulation it may be no more than in diameter at the thickest part and no more than in length. Although histor ...
to improve a batter's grip. Rule 1.10(c) of the 2002
Official rules of Major League Baseball The Official Rules of Major League Baseball is a set of rules set forth by the MLB governing the playing of baseball games by professional teams of Major League Baseball and the leagues that are members of the National Association of Professional ...
restricts application to the lower 18 inches of a bat. The most famous example of the rule being applied is the
Pine Tar Incident The Pine Tar Incident (also known as the Pine Tar Game) was a controversial incident in during an American League baseball game played between the Kansas City Royals and New York Yankees at Yankee Stadium in New York City on Sunday, July 24, 198 ...
, which occurred during the July 24, 1983 game between the
Kansas City Royals The Kansas City Royals are an American professional baseball team based in Kansas City, Missouri. The Royals compete in Major League Baseball (MLB) as a member club of the American League (AL) Central division. The team was founded as an expans ...
and
New York Yankees The New York Yankees are an American professional baseball team based in the Boroughs of New York City, New York City borough of the Bronx. The Yankees compete in Major League Baseball (MLB) as a member club of the American League (AL) Amer ...
which resulted in a
George Brett George Howard Brett (born May 15, 1953) is an American former professional baseball player who played all of his 21 seasons in Major League Baseball (MLB) as a third baseman for the Kansas City Royals. Brett's 3,154 career hits are second-mo ...
go-ahead home run in the ninth inning being nullified and the game being protested. Pine tar is also sometimes used illegally by pitchers to improve their grip on the ball in cold weather. This is not allowed due to a regulation prohibiting the application of any foreign substance to a ball (except grip-improving baseball rubbing mud applied by the umpires).


Medical

Pine tar has historically been used for treating skin conditions, usually as an additive in cold process solid soap or lotions. Due to the high presence of phenol in the early manufacturing of pine tar, it was deemed carcinogenic. However, now much of the phenol has been removed. Pine tar was banned by the FDA along with many other ingredients categorized as over the counter drugs, due to a lack of evidence of safety and effectiveness for the specific uses named.Drug products containing certain active ingredients offered over-the-counter (OTC) for certain uses. 14CFR310.545
/ref> However, clinical tests in Australia in 2017 demonstrated that the greatest risk comes from acute sensitivity for those with severe dermatological conditions, and if it comes in contact with the eyes. It is important to note that the number of positive reactions for wood tars was not significantly greater than those for other common allergens. In addition, the concentration of pine tar in topical products available in Australia is up to 2.3%, which is up to four times less than that tested in these studies. Pine tar has been used to cover peck wounds in captive bird flocks such as chickens, to prevent continued pecking on a wound and cannibalism. Pine tar is also used in veterinary medicine as an expectorant and an antiseptic in chronic skin conditions.''Merck Index'', 11th Edition, 7417. p. 1182


See also

*
Coal tar Coal tar is a thick dark liquid which is a by-product of the production of coke and coal gas from coal. It is a type of creosote. It has both medical and industrial uses. Medicinally it is a topical medication applied to skin to treat psoriasi ...
*
Creosote Creosote is a category of carbonaceous chemicals formed by the distillation of various tars and pyrolysis of plant-derived material, such as wood or fossil fuel. They are typically used as preservatives or antiseptics. Some creosote types were ...
*
Tarpaulin A tarpaulin ( , ) or tarp is a large sheet of strong, flexible, water-resistant or waterproof material, often cloth such as canvas or polyester coated with polyurethane, or made of plastics such as polyethylene. Tarpaulins often have reinforce ...
*
Tarring and feathering Tarring and feathering is a form of public torture and punishment used to enforce unofficial justice or revenge. It was used in feudal Europe and its colonies in the early modern period, as well as the early American frontier, mostly as a ty ...
(punishment)


References

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External links


History of Pine Tar
{{Wood products Wood products Food additives Non-timber forest products Baseball bats Maritime culture